Photocatalytic Fixation of Molecular Nitrogen in Systems Based on Graphite-Like Carbon Nitride: a Review
نویسندگان
چکیده
Cutting-edge research on graphite-like carbon nitride-based (g-C3N4) photocatalytic systems for molecular nitrogen fixation is summarized. The properties of modified g-C3N4 with grafted functional groups, structural defects (nitrogen or vacancies), doped nonmetals and metals, as well g-C3N4-based binary ternary composites the participation their oxides, metalates, carbonates, hydrocarbons, sulfides are discussed. most promising areas further outlined.
منابع مشابه
The function-led design of Z-scheme photocatalytic systems based on hollow carbon nitride semiconductors.
A ternary photocatalyst has been successfully constructed through the integration of Au, CdS and hollow carbon nitride nanospheres (HCNS), where Au nanoparticles were designed to shuttle interparticle transfer of charge carriers between CdS and HCNS photosensitizers to establish two-photon (Z-scheme) photocatalytic tandem systems for solar fuel production. The solid-state CdS-Au-HCNS Z-scheme n...
متن کاملNitrogen Fixation via a Terminal Fe(IV) Nitride.
Terminal iron nitrides (Fe≡N) have been proposed as intermediates of (bio)catalytic nitrogen fixation, yet experimental evidence to support this hypothesis has been lacking. In particular, no prior synthetic examples of terminal Fe≡N species have been derived from N2. Here we show that a nitrogen-fixing Fe-N2 catalyst can be protonated to form a neutral Fe(NNH2) hydrazido(2-) intermediate, whic...
متن کاملPreparation of graphite-like carbon nitride nanoflake film with strong fluorescent and electrochemiluminescent activity.
The preparation, characterization, fluorescence (FL) and electrochemiluminescence (ECL) of graphite-like carbon nitride nanoflake particles (g-C(3)N(4) NFPs) and nanoflake films (g-C(3)N(4) NFFs) have been reported. Highly water-dispersible g-C(3)N(4) NFPs with a height of ~5 to 35 nm and a lateral dimension of ~40 to 220 nm have been extracted from bulk g-C(3)N(4) materials by chemical oxidati...
متن کاملdesigning unmanned aerial vehicle based on neuro-fuzzy systems
در این پایان نامه، کنترل نرو-فازی در پرنده هدایت پذیر از دور (پهپاد) استفاده شده است ابتدا در روش پیشنهادی اول، کنترل کننده نرو-فازی توسط مجموعه اطلاعات یک کنترل کننده pid به صورت off-line آموزش دیده است و در روش دوم یک کنترل کننده نرو-فازی on-line مبتنی بر شناسایی سیستم توسط شبکه عصبی rbf پیشنهاد شده است. سپس کاربرد این کنترل کننده در پهپاد بررسی شده است و مقایسه ای ما بین کنترل کننده های معمو...
Crystallinity Modulation of Layered Carbon Nitride for Enhanced Photocatalytic Activities
As an emerging metal-free semiconductor, covalently bonded carbon nitride (CN) has attracted much attention in photocatalysis. However, drawbacks such as a high recombination rate of excited electrons and holes hinder its potential applications. Tailoring the crystallinity of semiconductors is an important way to suppress unwanted charge recombination, but has rarely been applied to CN so far. ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Theoretical and Experimental Chemistry
سال: 2021
ISSN: ['0040-5760', '1573-935X']
DOI: https://doi.org/10.1007/s11237-021-09678-2